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Acetic anhydride, or ethanoic anhydride, is the chemical compound with the formula (CH 3 CO) 2 O. Commonly abbreviated Ac 2 O , it is the simplest isolable anhydride of a carboxylic acid and is widely used as a reagent in organic synthesis .
This page contains tables of azeotrope data for various binary and ternary mixtures of solvents. The data include the composition of a mixture by weight (in binary azeotropes, when only one fraction is given, it is the fraction of the second component), the boiling point (b.p.) of a component, the boiling point of a mixture, and the specific gravity of the mixture.
Boiling point (°C) K b (°C⋅kg/mol) Freezing point (°C) K f (°C⋅kg/mol) Data source; ... Acetic Anhydride: 139.0 [6] Ethylene Dichloride: 1.25 83.5 −35 [7 ...
Melting point: 76 to 77 °C (169 to 171 °F; 349 to 350 K) Boiling point: 265.5 °C (509.9 °F; 538.6 K) ... (in the form of an acid anhydride), such as with acetic ...
Triple point: 289.8 K (16.7 °C), ? Pa Critical point: 593 K (320 °C), 57.8 bar Eutectic point with water –26.7 °C Std enthalpy change of fusionΔ fus H o +11.7 kJ/mol Std entropy change of fusionΔ fus S o: 40.5 J/(mol·K) Std enthalpy change of vaporizationΔ vap H o +23.7 kJ/mol Std entropy change of vaporizationΔ vap S o? J/(mol·K ...
Acetone and acetic anhydride ((CH 3 C(O)) 2 O) upon the addition of boron trifluoride (BF 3) catalyst: [11] (CH 3 C(O)) 2 O + CH 3 C(O)CH 3 → CH 3 C(O)CH 2 C(O)CH 3 A second synthesis involves the base-catalyzed condensation (e.g., by sodium ethoxide CH 3 CH 2 O − Na + ) of acetone and ethyl acetate , followed by acidification of the sodium ...
In the laboratory, it can be easily synthesized from anthranilic acid and acetic anhydride. N-Acetylanthranilic acid exhibits triboluminescence when crushed. [5] The fractured crystals have large electrical potentials between areas of high and low charge.
Melting point: 206 to 208 °C (403 to 406 °F; 479 to 481 K) ... or with an equal molar amount of acetic anhydride in glacial (concentrated) acetic acid. ...