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Chemisorption is a kind of adsorption which involves a chemical reaction between the surface and the adsorbate. New chemical bonds are generated at the adsorbent surface. Examples include macroscopic phenomena that can be very obvious, like corrosion [clarification needed], and subtler effects associated with heterogeneous catalysis, where the catalyst and reactants are in different pha
Sorption is a physical and chemical process by which one substance becomes attached to another. Specific cases of sorption are treated in the following articles: Specific cases of sorption are treated in the following articles:
Adsorption is present in many natural, physical, biological and chemical systems and is widely used in industrial applications such as heterogeneous catalysts, [9] [10] activated charcoal, capturing and using waste heat to provide cold water for air conditioning and other process requirements (adsorption chillers), synthetic resins, increasing ...
BET theory applies to systems of multilayer adsorption that usually utilizes a probing gas (called the adsorbate) that does not react chemically with the adsorptive (the material upon which the gas attaches to) to quantify specific surface area. Nitrogen is the most commonly employed gaseous adsorbate for probing surface(s).
Chemisorption often involves an activation energy. For physisorption gas phase molecules, adsorbates, form multilayer adsorption unless physical barriers, such as porosity, interfere. In chemisorption, molecules are adsorbed on the surface by valence bonds and only form monolayer adsorption.
Adsorption is the adhesion of ions or molecules onto the surface of another phase. [1] Adsorption may occur via physisorption and chemisorption. Ions and molecules can adsorb to many types of surfaces including polymer surfaces.
where R is the gas constant (8.314 J mol −1 K −1), T the temperature (K), Φ v,fresh, the flow rate of the fresh water outflow (m 3 /s), C feed the concentration of ions in the feed water (mol/m 3) and C fresh the ion concentration in the fresh water outflow (mol/m 3) of the CDI cell.
The oxidation of hydrocarbons to water and carbon dioxide: 2 C 6 H 6 + 15 O 2 → 12 CO 2 + 6 H 2 O; This process can occur with any of hydrocarbon, but most commonly is performed with petrol or diesel. Asymmetric heterogeneous catalysis facilitates the production of pure enantiomer compounds using chiral heterogeneous catalysts. [26]