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Very high thermal conductivity measurements up to 22,600 w m −1 K −1 were reported by Fenton, E.W., Rogers, J.S. and Woods, S.D. in reference 570 on page 1458, 41, 2026–33, 1963. The data is listed on pages 6 through 8 and graphed on page 1 where Fenton and company are on curves 63 and 64.
SiC–SiC composites have a relatively high thermal conductivity and can operate at very high temperatures due to their inherently high creep and oxidation resistance. Residual porosity and stoichiometry of the material can vary its thermal conductivity, with increasing porosity leading to lower thermal conductivity and presence of Si–O–C ...
For example, carbon fibers are commonly used in aluminium matrix to synthesize composites showing low density and high strength. However, carbon reacts with aluminium to generate a brittle and water-soluble compound Al 4 C 3 on the surface of the fiber. To prevent this reaction, the carbon fibers are coated with nickel or titanium boride.
AlSiC, pronounced "alsick", [1] is a metal matrix composite consisting of aluminium matrix with silicon carbide particles. It has high thermal conductivity (180–200 W/m K), and its thermal expansion can be adjusted to match other materials, e.g. silicon and gallium arsenide chips and various ceramics.
However, for dimensions below 7 to 10 nm nodes, the decreased volume of available conducting metal will force innovative material and integration approaches towards novel interconnect architectures. Also for power and high-performance applications the most critical challenges are high ampacity, thermal conductivity and electromigration resistance.
This is achieved by depositing a thin layer of pyrolytic carbon or boron nitride on the fibers, which weakens the bond at the fiber/matrix interface, leading to the fiber pull-out at crack surfaces, as shown in the SEM picture at the top of this article. In oxide-CMCs, the high porosity of the matrix is sufficient to establish a weak bond.
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