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The automatic calculation of particle interaction or decay is part of the computational particle physics branch. It refers to computing tools that help calculating the complex particle interactions as studied in high-energy physics, astroparticle physics and cosmology.
The helicity of a particle is positive (" right-handed") if the direction of its spin is the same as the direction of its motion and negative ("left-handed") if opposite. Helicity is conserved. [1] That is, the helicity commutes with the Hamiltonian, and thus, in the absence of external forces, is time-invariant. It is also rotationally ...
According to transition state theory, the smallest fraction of the catalytic cycle is spent in the most important step, that of the transition state. The original proposals of absolute reaction rate theory for chemical reactions defined the transition state as a distinct species in the reaction coordinate that determined the absolute reaction rate.
The two-component helicity eigenstates satisfy ^ (^) = (^) where are the Pauli matrices, ^ is the direction of the fermion momentum, = depending on whether spin is pointing in the same direction as ^ or opposite.
Entropy of activation determines the preexponential factor A of the Arrhenius equation for temperature dependence of reaction rates. The relationship depends on the molecularity of the reaction: for reactions in solution and unimolecular gas reactions A = (ek B T/h) exp(ΔS ‡ /R), while for bimolecular gas reactions A = (e 2 k B T/h) (RT/p ...
The concept of a transition state has been important in many theories of the rates at which chemical reactions occur. This started with the transition state theory (also referred to as the activated complex theory), which was first developed around 1935 by Eyring, Evans and Polanyi, and introduced basic concepts in chemical kinetics that are still used today.
where A and B are reactants C is a product a, b, and c are stoichiometric coefficients,. the reaction rate is often found to have the form: = [] [] Here is the reaction rate constant that depends on temperature, and [A] and [B] are the molar concentrations of substances A and B in moles per unit volume of solution, assuming the reaction is taking place throughout the volume of the ...
Chemical kinetics, also known as reaction kinetics, is the branch of physical chemistry that is concerned with understanding the rates of chemical reactions. It is different from chemical thermodynamics, which deals with the direction in which a reaction occurs but in itself tells nothing about its rate.