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  2. Equilibrium constant - Wikipedia

    en.wikipedia.org/wiki/Equilibrium_constant

    The equilibrium constant of a chemical reaction is the value of its reaction quotient at chemical equilibrium, a state approached by a dynamic chemical system after sufficient time has elapsed at which its composition has no measurable tendency towards further change. For a given set of reaction conditions, the equilibrium constant is ...

  3. Van 't Hoff equation - Wikipedia

    en.wikipedia.org/wiki/Van_'t_Hoff_equation

    The Van 't Hoff equation relates the change in the equilibrium constant, K eq, of a chemical reaction to the change in temperature, T, given the standard enthalpy change, Δ r H ⊖, for the process. The subscript r {\displaystyle r} means "reaction" and the superscript ⊖ {\displaystyle \ominus } means "standard".

  4. Chemical equilibrium - Wikipedia

    en.wikipedia.org/wiki/Chemical_equilibrium

    When pure substances (liquids or solids) are involved in equilibria their activities do not appear in the equilibrium constant [14] because their numerical values are considered one. Applying the general formula for an equilibrium constant to the specific case of a dilute solution of acetic acid in water one obtains CH 3 CO 2 H + H 2 O ⇌ CH 3 ...

  5. Determination of equilibrium constants - Wikipedia

    en.wikipedia.org/wiki/Determination_of...

    The value of the equilibrium constant for the formation of a 1:1 complex, such as a host-guest species, may be calculated with a dedicated spreadsheet application, Bindfit: [4] In this case step 2 can be performed with a non-iterative procedure and the pre-programmed routine Solver can be used for step 3.

  6. Arrhenius equation - Wikipedia

    en.wikipedia.org/wiki/Arrhenius_equation

    In physical chemistry, the Arrhenius equation is a formula for the temperature dependence of reaction rates.The equation was proposed by Svante Arrhenius in 1889, based on the work of Dutch chemist Jacobus Henricus van 't Hoff who had noted in 1884 that the van 't Hoff equation for the temperature dependence of equilibrium constants suggests such a formula for the rates of both forward and ...

  7. Equilibrium chemistry - Wikipedia

    en.wikipedia.org/wiki/Equilibrium_chemistry

    The free concentrations are calculated by solving the equations of mass-balance, and the concentrations of the complexes are calculated using the equilibrium constant definitions. A quantity corresponding to the observed quantity can then be calculated using physical principles such as the Nernst potential or Beer-Lambert law which relate the ...

  8. Acid dissociation constant - Wikipedia

    en.wikipedia.org/wiki/Acid_dissociation_constant

    In chemistry, an acid dissociation constant (also known as acidity constant, or acid-ionization constant; denoted ⁠ ⁠) is a quantitative measure of the strength of an acid in solution. It is the equilibrium constant for a chemical reaction

  9. Buffer solution - Wikipedia

    en.wikipedia.org/wiki/Buffer_solution

    This follows from the equilibrium expression. The third row, labelled E for "equilibrium", adds together the first two rows and shows the concentrations at equilibrium. To find x, use the formula for the equilibrium constant in terms of concentrations: = [+] [] [].