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A monosubstituted cyclohexane is one in which there is one non-hydrogen substituent in the cyclohexane ring. The most energetically favorable conformation for a monosubstituted cyclohexane is the chair conformation with the non-hydrogen substituent in the equatorial position because it prevents high steric strain from 1,3 diaxial interactions. [11]
A-values help predict the conformation of cyclohexane rings. The most stable conformation will be the one which has the substituent or substituents equatorial. When multiple substituents are taken into consideration, the conformation where the substituent with the largest A-value is equatorial is favored.
Another conformation of cyclohexane exists, known as boat conformation, but it interconverts to the slightly more stable chair formation. If cyclohexane is mono-substituted with a large substituent , then the substituent will most likely be found attached in an equatorial position, as this is the slightly more stable conformation .
The anti conformation is more stable by 0.9 kcal mol −1. [1] We would expect that butane is roughly 82% anti and 18% gauche at room temperature. However, there are two possible gauche conformations and only one anti conformation. Therefore, entropy makes a contribution of 0.4 kcal in favor of the gauche conformation. [2]
The cis isomer is already in the correct geometry in its most stable conformation; therefore, it eliminates easily. The repulsion between an axial t -butyl group and hydrogen atoms in the 1,3-diaxial position is so strong that the cyclohexane ring will revert to a twisted boat conformation.
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As stated above, a chair flip is a ring inversion specifically of cyclohexane (and its derivatives) from one chair conformer to another, often to reduce steric strain.The term, "flip" is misleading, because the direction of each carbon remains the same; what changes is the orientation.
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