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Equilibrium reaction relating the two tautomers of bisulfite. The bisulfite ion (IUPAC-recommended nomenclature: hydrogensulfite) is the ion HSO − 3. Salts containing the HSO − 3 ion are also known as "sulfite lyes". [1] Sodium bisulfite is used interchangeably with sodium metabisulfite (Na 2 S 2 O 5).
Sodium bisulfate, also known as sodium hydrogen sulfate, [a] is the sodium salt of the bisulfate anion, with the molecular formula NaHSO 4. Sodium bisulfate is an acid salt formed by partial neutralization of sulfuric acid by an equivalent of sodium base, typically in the form of either sodium hydroxide (lye) or sodium chloride (table salt).
The sulfate ion carries an overall charge of −2 and it is the conjugate base of the bisulfate (or hydrogensulfate) ion, HSO − 4, which is in turn the conjugate base of H 2 SO 4, sulfuric acid. Organic sulfate esters, such as dimethyl sulfate, are covalent compounds and esters of sulfuric acid.
Sodium bisulfite (or sodium bisulphite, sodium hydrogen sulfite) is a chemical mixture with the approximate chemical formula NaHSO 3. Sodium bisulfite is not a real compound, [ 2 ] but a mixture of salts that dissolve in water to give solutions composed of sodium and bisulfite ions.
An amphiprotic molecule (or ion) can either donate or accept a proton, thus acting either as an acid or a base. Water, amino acids, hydrogencarbonate ion (or bicarbonate ion) HCO − 3, dihydrogen phosphate ion H 2 PO − 4, and hydrogensulfate ion (or bisulfate ion) HSO − 4 are common examples of amphiprotic species. Since they can donate a ...
Sulfites or sulphites are compounds that contain the sulfite ion (or the sulfate(IV) ion, from its correct systematic name), SO 2− 3. The sulfite ion is the conjugate base of bisulfite. Although its acid (sulfurous acid) is elusive, [1] its salts are widely used. Sulfites are substances that naturally occur in some foods and the human body.
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An alternative protocol uses a solution of iodate ion (for instance potassium iodate) to which an acidified solution (again with sulfuric acid) of sodium bisulfite is added. [3] In this protocol, iodide ion is generated by the following slow reaction between the iodate and bisulfite: IO − 3 + 3 HSO − 3 → I − + 3 HSO − 4