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An intramolecular force (from Latin intra-'within') is any force that binds together the atoms making up a molecule. [1] Intramolecular forces are stronger than the intermolecular forces that govern the interactions between molecules.
Many reactions in organic chemistry can occur in either an intramolecular or intermolecular senses. Some reactions are by definition intramolecular or are only practiced intramolecularly, e.g., Dieckmann condensation of diesters is the intramolecular version of aldol condensation. Madelung synthesis of indoles; Smiles rearrangement
An intermolecular force (IMF; also secondary force) is the force that mediates interaction between molecules, including the electromagnetic forces of attraction or repulsion which act between atoms and other types of neighbouring particles, e.g. atoms or ions.
In chemistry, intervalence charge transfer, often abbreviated IVCT or even IT, is a type of charge-transfer band that is associated with mixed valence compounds. It is most common for systems with two metal sites differing only in oxidation state. Quite often such electron transfer reverses the oxidation states of the sites.
In organic chemistry, a rearrangement reaction is a broad class of organic reactions where the carbon skeleton of a molecule is rearranged to give a structural isomer of the original molecule. [1] Often a substituent moves from one atom to another atom in the same molecule, hence these reactions are usually intramolecular. In the example below ...
Lessons in Chemistry is finally on AppleTV+, which means fans of Bonnie Garmus’ bestselling novel are on the lookout for any and all ways the show is different from its beloved source material.
Ligation is complicated by the fact that the reaction can involve both inter- and intra-molecular reactions, but the desired ligation products in many ligation reactions (e.g. ligating a DNA fragment into a vector) needed first to be inter-molecular, i.e. between two different DNA molecules, followed by an intra-molecular reaction to seal and ...
Let the playoffs commence. A first-of-its-kind College Football Playoff officially kicks off Friday at 8 p.m. ET with No. 9 Indiana taking the three-hour-plus drive north US-31 to Notre Dame ...