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Immersion zinc plating is an electroless (non-electrolytic) coating process that deposits a thin layer of zinc on a less electronegative metal, by immersion in a solution containing a zinc or zincate ions, Zn(OH) 2− 4. A typical use is plating aluminum with zinc prior to electrolytic or electroless nickel plating.
Zinc-nickel plating is one of the best corrosion resistant finishes available offering over 5 times the protection of conventional zinc plating and up to 1,500 hours of neutral salt spray test performance. This plating is a combination of a high-nickel zinc-nickel alloy (10–15% nickel) and some variation of chromate.
Such zinc electroplating or zinc alloy electroplating maintains a dominant position among other electroplating process options, based upon electroplated tonnage per annum. According to the International Zinc Association, more than 5 million tons are used yearly for both hot-dip galvanization and electroplating. [ 1 ]
"Black nickel" is a dark coating that consists primarily of nickel sulfide and metallic zinc and nickel. [14] It is typically plated on brass, bronze, or steel in order to produce a non-reflective surface. [15] This type of plating is used for decorative and military purposes and does not offer much protection. [1] [2] [15]
A phosphate coating is usually obtained by applying to the steel part a dilute solution of phosphoric acid, possibly with soluble iron, zinc, and/or manganese salts. The solution may be applied by sponging, spraying, or immersion. [6] Phosphate conversion coatings can also be used on aluminium, zinc, cadmium, silver and tin. [7] [8]
Nickel plating Soon after, John Wright of Birmingham , England discovered that potassium cyanide was a suitable electrolyte for gold and silver electroplating. Wright's associates, George Elkington and Henry Elkington were awarded the first patents for electroplating in 1840.
Because electrolytically zinc-plated surfaces provide comparatively little corrosion protection, and in the case of galvanic zinc coatings on high-strength steel (e.g. category 10.9 and 12.9 high-strength bolts) there is a risk of hydrogen embrittlement, the industry needed a better corrosion protection system.
A conversion coating is a chemical or electro-chemical treatment applied to manufactured parts that superficially converts the material into a thin adhering coating of an insoluble compound.
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