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A molecular vibration is a periodic motion of the atoms of a molecule relative to each other, such that the center of mass of the molecule remains unchanged. The typical vibrational frequencies range from less than 10 13 Hz to approximately 10 14 Hz, corresponding to wavenumbers of approximately 300 to 3000 cm −1 and wavelengths of approximately 30 to 3 μm.
The frequency depends only weakly on the wavelength of the oscillation. The quasiparticle resulting from the quantization of these oscillations is the plasmon. Langmuir waves were discovered by American physicists Irving Langmuir and Lewi Tonks in the 1920s. [1]
In the physical sciences, the wavenumber (or wave number), also known as repetency, [1] is the spatial frequency of a wave, measured in cycles per unit distance (ordinary wavenumber) or radians per unit distance (angular wavenumber). [2][3][4] It is analogous to temporal frequency, which is defined as the number of wave cycles per unit time ...
Surface plasmon. Schematic representation of an electron density wave propagating along a metal– dielectric interface. The charge density oscillations and associated electromagnetic fields are called surface plasmon-polariton waves. The exponential dependence of the electromagnetic field intensity on the distance away from the interface is ...
The waves in quantum systems are oscillations in probability amplitude rather than material displacement. The frequency of oscillation, f, relates to the mode energy by E = hf where h is the Planck constant. Thus a system like an atom consists of a linear combination of modes of definite energy. These energies are characteristic of the ...
where λ is the wavelength of an emitted photon, ν is its frequency, E is the photon energy, h is the Planck constant, and c is the speed of light. In a laboratory setting, the hydrogen line parameters have been more precisely measured as: λ = 21.106 114 054 160 (30) cm ν = 1 420 405 751.768(2) Hz. in a vacuum. [3]
The frequency of oscillation at x is proportional to the momentum p(x) of a classical particle of energy E n and position x. Furthermore, the square of the amplitude (determining the probability density) is inversely proportional to p(x), reflecting the length of time the classical particle spends near x.
In physics, a wave vector (or wavevector) is a vector used in describing a wave, with a typical unit being cycle per metre. It has a magnitude and direction. Its magnitude is the wavenumber of the wave (inversely proportional to the wavelength), and its direction is perpendicular to the wavefront. In isotropic media, this is also the direction ...