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The electrospray ionization technique was first reported by Masamichi Yamashita and John Fenn in 1984, [3] and independently by Lidia Gall and co-workers in Soviet Union, also in 1984. [4] Gall's work was not recognised or translated in the western scientific literature until a translation was published in 2008. [4]
In 1914, John Zeleny published work on the behaviour of fluid droplets at the end of glass capillaries. [5] This report presents experimental evidence for several electrospray operating regimes (dripping, burst, pulsating, and cone-jet). [6] A few years later, Zeleny captured the first time-lapse images of the dynamic liquid meniscus. [7]
Desorption electrospray ionization (DESI) is an ambient ionization technique that can be coupled to mass spectrometry (MS) for chemical analysis of samples at atmospheric conditions. Coupled ionization sources-MS systems are popular in chemical analysis because the individual capabilities of various sources combined with different MS systems ...
ESTASI is a contactless process based on capacitive coupling. One advantage of ESTASI is, that the electrode and sample droplet act contact-less avoiding thereby any oxidation or reduction of the sample compounds at the electrode surface, which often happens during standard electrospray ionization (ESI). [2]
Extractive electrospray ionization (EESI) [1] [2] is a spray-type, ambient ionization source [3] [4] [5] [6] [7] in mass spectrometry that uses two colliding aerosols ...
Schematic diagram of ion trap mass spectrometer with an electrospray ionization (ESI) source and Paul ion trap. A Paul trap is a type of quadrupole ion trap that uses static direct current (DC) and radio frequency (RF) oscillating electric fields to trap ions. Paul traps are commonly used as components of a mass spectrometer.
In mass spectrometry, direct analysis in real time (DART) is an ion source that produces electronically or vibronically excited-state species from gases such as helium, argon, or nitrogen that ionize atmospheric molecules or dopant molecules.
This cone was described by Sir Geoffrey Ingram Taylor in 1964 before electrospray was "discovered". [1] This work followed on the work of Zeleny [2] who photographed a cone-jet of glycerine in a strong electric field and the work of several others: Wilson and Taylor (1925), [3] Nolan (1926) [4] and Macky (1931). [5]