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Phosphorus pentabromide is a reactive, yellow solid of formula P Br 5, which has the structure [PBr 4] + Br − (tetrabromophosphonium bromide) in the solid state but in the vapor phase is completely dissociated to PBr 3 and Br 2.
Binary hydrogen compounds in group 1 are the ionic hydrides (also called saline hydrides) wherein hydrogen is bound electrostatically. Because hydrogen is located somewhat centrally in an electronegative sense, it is necessary for the counterion to be exceptionally electropositive for the hydride to possibly be accurately described as truly behaving ionic.
Solid hydrogen is the solid state of the element hydrogen. At standard pressure , this is achieved by decreasing the temperature below hydrogen's melting point of 14.01 K (−259.14 °C; −434.45 °F).
The solid form has a hexagonal crystalline structure and is soft and easily crushed. Hydrogen is an insulator in all of its forms. It has a high ionisation energy (1312.0 kJ/mol), moderate electron affinity (73 kJ/mol), and moderate electronegativity (2.2). Hydrogen is a poor oxidising agent (H 2 + 2e − → 2H – = –2.25 V at pH 0). Its ...
Hydrogen compounds are compounds containing the element hydrogen. In these compounds, hydrogen can form in the +1 and -1 oxidation states. Hydrogen can form compounds both ionically and in covalent substances. It is a part of many organic compounds such as hydrocarbons as well as water and other organic substances.
formula system space group unit cell Å volume density comment ref Ca 2 PBr : cubic I 4 3d: a=5.96 Z=2 red brown [1]Ca 2 PBr : hexagonal R 3 m: a=4.23 c=20.9 Z=3 [1]Cu 12 P 20 Br 10: triclinic
Phosphorus(II) halides may be prepared by passing an electric discharge through a mixture of the trihalide vapour and hydrogen gas. [citation needed] The relatively stable P 2 I 4 is known to have a trans, bent configuration similar to hydrazine and finds some uses in organic syntheses, the others are of purely academic interest at the present ...
Hydrogen auto-transfer, also known as borrowing hydrogen, is the activation of a chemical reaction by temporary transfer of two hydrogen atoms from the reactant to a catalyst and return of those hydrogen atoms back to a reaction intermediate to form the final product.