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  2. Hume-Rothery rules - Wikipedia

    en.wikipedia.org/wiki/Hume-Rothery_rules

    [5] [6] The solute and solvent should have similar electronegativity. [7] Valency factor: two elements should have the same valence. The greater the difference in valence between solute and solvent atoms, the lower the solubility.

  3. VSEPR theory - Wikipedia

    en.wikipedia.org/wiki/VSEPR_theory

    The bond angle for water is 104.5°. Valence shell electron pair repulsion (VSEPR) theory (/ ˈ v ɛ s p ər, v ə ˈ s ɛ p ər / VESP-ər, [1]: 410 və-SEP-ər [2]) is a model used in chemistry to predict the geometry of individual molecules from the number of electron pairs surrounding their central atoms. [3]

  4. Pauling's rules - Wikipedia

    en.wikipedia.org/wiki/Pauling's_rules

    For a given cation, Pauling defined [2] the electrostatic bond strength to each coordinated anion as =, where z is the cation charge and ν is the cation coordination number. A stable ionic structure is arranged to preserve local electroneutrality , so that the sum of the strengths of the electrostatic bonds to an anion equals the charge on ...

  5. Bond valence method - Wikipedia

    en.wikipedia.org/wiki/Bond_valence_method

    The bond valence method or mean method (or bond valence sum) (not to be mistaken for the valence bond theory in quantum chemistry) is a popular method in coordination chemistry to estimate the oxidation states of atoms. It is derived from the bond valence model, which is a simple yet robust model for validating chemical structures with ...

  6. Valence (chemistry) - Wikipedia

    en.wikipedia.org/wiki/Valence_(chemistry)

    The valence is the combining capacity of an atom of a given element, determined by the number of hydrogen atoms that it combines with. In methane, carbon has a valence of 4; in ammonia, nitrogen has a valence of 3; in water, oxygen has a valence of 2; and in hydrogen chloride, chlorine has a valence of 1. Chlorine, as it has a valence of one ...

  7. Chemical polarity - Wikipedia

    en.wikipedia.org/wiki/Chemical_polarity

    When comparing a polar and nonpolar molecule with similar molar masses, the polar molecule in general has a higher boiling point, because the dipole–dipole interaction between polar molecules results in stronger intermolecular attractions. One common form of polar interaction is the hydrogen bond, which is also

  8. Metal ions in aqueous solution - Wikipedia

    en.wikipedia.org/wiki/Metal_ions_in_aqueous_solution

    A metal ion in aqueous solution or aqua ion is a cation, dissolved in water, of chemical formula [M(H 2 O) n] z+.The solvation number, n, determined by a variety of experimental methods is 4 for Li + and Be 2+ and 6 for most elements in periods 3 and 4 of the periodic table.

  9. Ionic strength - Wikipedia

    en.wikipedia.org/wiki/Ionic_strength

    The molar ionic strength, I, of a solution is a function of the concentration of all ions present in that solution. [3]= = where one half is because we are including both cations and anions, c i is the molar concentration of ion i (M, mol/L), z i is the charge number of that ion, and the sum is taken over all ions in the solution.