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2,2′-Dipyridyldisulfide, sometimes known as DPS, is used for preparing thiols [1] [2] and activating carboxylic acid for coupling reactions, as in the following reaction: [3] Uses [ edit ]
The Dortmund Data Bank [1] (short DDB) is a factual data bank for thermodynamic and thermophysical data. Its main usage is the data supply for process simulation where experimental data are the basis for the design, analysis, synthesis, and optimization of chemical processes .
Collision frequency describes the rate of collisions between two atomic or molecular species in a given volume, per unit time. In an ideal gas, assuming that the species behave like hard spheres, the collision frequency between entities of species A and species B is: [1]
Disintegrations per minute (dpm) and disintegrations per second (dps) are measures of the activity of the source of radioactivity. The SI unit of radioactivity, the becquerel (Bq), is equivalent to one disintegration per second. This unit should not be confused with cps, which is the number of counts received by an instrument from the source.
Z can be converted to mole collision per liter per second dividing by 1000N A. If all the units that are related to dimension are converted to dm, i.e. mol⋅dm −3 for [A] and [B], dm 2 for σ AB, dm 2 ⋅kg⋅s −2 ⋅K −1 for the Boltzmann constant, then
where A and B are reactants C is a product a, b, and c are stoichiometric coefficients,. the reaction rate is often found to have the form: = [] [] Here is the reaction rate constant that depends on temperature, and [A] and [B] are the molar concentrations of substances A and B in moles per unit volume of solution, assuming the reaction is taking place throughout the volume of the ...
[1] [2] It is usually given in units of becquerel per kilogram (Bq/kg), but another commonly used unit of specific activity is the curie per gram (Ci/g). In the context of radioactivity , activity or total activity (symbol A ) is a physical quantity defined as the number of radioactive transformations per second that occur in a particular ...
Spartan is a molecular modelling and computational chemistry application from Wavefunction. [2] It contains code for molecular mechanics, semi-empirical methods, ab initio models, [3] density functional models, [4] post-Hartree–Fock models, [5] and thermochemical recipes including G3(MP2) [6] and T1. [7]