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In industrial chemistry, coal gasification is the process of producing syngas—a mixture consisting primarily of carbon monoxide (CO), hydrogen (H 2), carbon dioxide (CO 2), methane (CH 4), and water vapour (H 2 O)—from coal and water, air and/or oxygen. Historically, coal was gasified to produce coal gas, also known as "town gas".
The syngas production can lead to the hydrogen production from the downstream water-gas shift reaction. The CLG process can also be applied to electricity generation, resembling the IGCC based on the syngas generated from the chemical looping processes.
The chemical composition of syngas varies based on the raw materials and the processes. Syngas produced by coal gasification generally is a mixture of 30 to 60% carbon monoxide, 25 to 30% hydrogen, 5 to 15% carbon dioxide, and 0 to 5% methane. It also contains lesser amount of other gases. [10]
Below is a schematic flow diagram of an IGCC plant: Block diagram of IGCC power plant, which utilizes the HRSG. The gasification process can produce syngas from a wide variety of carbon-containing feedstocks, such as high-sulfur coal, heavy petroleum residues, and biomass.
Known as the Eastman Integrated Coal Gasification facility, it first opened in 1983 and is designed to process syngas from the gasification of Southwest Virginia and Eastern Kentucky coal, using Texaco gasifiers (now GE gasifier technology [15]). The intermediate products of syngas conversion are methanol and CO; these are further converted ...
The STG+ process eliminates multiple condensation and evaporation, and the process converts syngas to liquid transportation fuels directly without producing intermediate liquids. [7] This eliminates the need for storage of two products, including pressure storage for liquefied petroleum gas and storage of liquid methanol.
Multiple types of solid fuel gasifiers are commercially available for coal, petcoke, and biomass gasification.Designs vary depending on fuel and intended application. As a result, they can differ in the composition of the syngas produced and the efficiency with which they convert coal energy content to syngas energy content - a performance parameter typically termed cold gas efficiency. [3]
Underground coal gasification (UCG) is an industrial process which converts coal into product gas. UCG is an in-situ gasification process, carried out in non-mined coal seams using injection of oxidants and steam. The product gas is brought to the surface through production wells drilled from the surface. [1]