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Graphene is a semimetal whose conduction and valence bands meet at the Dirac points, which are six locations in momentum space, the vertices of its hexagonal Brillouin zone, divided into two non-equivalent sets of three points. The two sets are labeled K and K′. The sets give graphene a valley degeneracy of gv = 2.
Graphene (/ ˈ ɡ r æ f iː n /) [1] is a carbon allotrope consisting of a single layer of atoms arranged in a honeycomb planar nanostructure. [2] [3] The name "graphene" is derived from "graphite" and the suffix -ene, indicating the presence of double bonds within the carbon structure.
Graphene is the only form of carbon (or solid material) in which every atom is available for chemical reaction from two sides (due to the 2D structure). Atoms at the edges of a graphene sheet have special chemical reactivity. Graphene has the highest ratio of edge atoms of any allotrope. Defects within a sheet increase its chemical reactivity. [1]
A rapidly increasing list of graphene production techniques have been developed to enable graphene's use in commercial applications. [1]Isolated 2D crystals cannot be grown via chemical synthesis beyond small sizes even in principle, because the rapid growth of phonon density with increasing lateral size forces 2D crystallites to bend into the third dimension. [2]
A graphene helix, similar to the carbon nanotube, is a structure consisting of a two-dimensional sheet of graphene wrapped into a helix.These graphene sheets can have multiple layers, called multi-walled carbon structures, that add to these helices thus increasing their tensile strength but increasing the difficulty of manufacturing.
A two-dimensional semiconductor (also known as 2D semiconductor) is a type of natural semiconductor with thicknesses on the atomic scale. Geim and Novoselov et al. initiated the field in 2004 when they reported a new semiconducting material graphene, a flat monolayer of carbon atoms arranged in a 2D honeycomb lattice. [1]
Graphene-metal composites can be used in thermal interface materials. [194] Adding a layer of graphene to each side of a copper film increased the metal's heat-conducting properties up to 24%. This suggests the possibility of using them for semiconductor interconnects in computer chips.
The induced charge carriers of metal/graphene hybrid nanostructure could be up to 7 times higher than that of pristine graphene ones due to the plasmonic enhancement. So far, the graphene plasmonic effects have been demonstrated for different applications ranging from light modulation [15] [16] to biological/chemical sensing.
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