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The pinacol–pinacolone rearrangement is a method for converting a 1,2-diol to a carbonyl compound in organic chemistry. The 1,2-rearrangement takes place under acidic conditions. The name of the rearrangement reaction comes from the rearrangement of pinacol to pinacolone .
The pinacol coupling can be followed up by a pinacol rearrangement. A related reaction is the McMurry reaction , which uses titanium(III) chloride or titanium(IV) chloride in conjunction with a reducing agent for the formation of the metal-diol complex, and which takes place with an additional deoxygenation reaction step in order to provide an ...
A common migration introduction of carbon is a pinacol rearrangement. [1] While this reaction refers specifically to a vicinal dihydroxide rearrangement, there are other pinacol type rearrangements that proceed through the same general mechanism such as the Tiffeneau–Demjanov rearrangement.
In the pinacol rearrangement, the order of migratory aptitude has not been determined unambiguously, [2] but some trends have been determined. For example, relative migratory aptitudes for alkyl substituents is Hydride >C(CH 3) 3 > C 2 H 5 > phenyl > CH 3. [2] More bulky groups have more tendency to migrate.
Created Date: 8/30/2012 4:52:52 PM
He also discovered what is now known as the pinacol rearrangement, whereby 1,2-diols rearrange to aldehydes or ketones under acid catalysis. [ 4 ] [ 5 ] His work involved the preparation of 2,3-dimethyl-2,3-butanediol ( pinacol ) from acetone , [ 6 ] followed by the rearrangement to 3,3-dimethylbutanone ( pinacolone ), which was then oxidised ...
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o o o s. c: o thO 00 . Created Date: 9/20/2007 3:37:18 PM