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The data below tabulates standard electrode potentials (E°), in volts relative to the standard hydrogen electrode (SHE), at: Temperature 298.15 K (25.00 °C; 77.00 °F); Effective concentration (activity) 1 mol/L for each aqueous or amalgamated (mercury-alloyed) species; Unit activity for each solvent and pure solid or liquid species; and
If dissolved in pure water, the pH is halfway between these two pKa values. Purine is aromatic, having four tautomers each with a hydrogen bonded to a different one of the four nitrogen atoms. These are identified as 1-H, 3-H, 7-H, and 9-H (see image of numbered ring).
The following table lists the Van der Waals constants (from the Van der Waals equation) for a number of common gases and volatile liquids. [ 1 ] To convert from L 2 b a r / m o l 2 {\displaystyle \mathrm {L^{2}bar/mol^{2}} } to L 2 k P a / m o l 2 {\displaystyle \mathrm {L^{2}kPa/mol^{2}} } , multiply by 100.
pKa values for acetic, chloroacetic, dichloroacetic and trichloroacetic acids. Inductive effects and mesomeric effects affect the p K a values. A simple example is provided by the effect of replacing the hydrogen atoms in acetic acid by the more electronegative chlorine atom.
and to cite the cologarithm, pK a, of the value of this quantity in books and other publications. The two values are constrained by the relationship log K(association) * log K(dissociation) = pK w. pK w refers to the self-ionization of water: pK = log (1/K) = -log(K). Further monomeric complexes may be formed in a stepwise manner.
Hydrazoic acid, also known as hydrogen azide, azic acid or azoimide, [2] is a compound with the chemical formula HN 3. [3] It is a colorless, volatile, and explosive liquid at room temperature and pressure. It is a compound of nitrogen and hydrogen, and is therefore a pnictogen hydride. It was first isolated in 1890 by Theodor Curtius. [4]
In general, pK a values in water and organic solvent diverge significantly when the anion is capable of hydrogen bonding. For instance, in the case of water, the values differ dramatically: the pK a in water of water is 14.0, [15] while the pK a in DMSO of water is 31.4, [16] reflecting the differing ability of water and DMSO to stabilize the ...
Many of the highly radioactive elements have values that must be predictions or extrapolations, but are unfortunately not marked as such. This is especially problematic for francium, which by relativistic calculations can be shown to be less electronegative than caesium, but for which the only value (0.7) in the literature predates these ...