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The Planck relation [1] [2] [3] (referred to as Planck's energy–frequency relation, [4] the Planck–Einstein relation, [5] Planck equation, [6] and Planck formula, [7] though the latter might also refer to Planck's law [8] [9]) is a fundamental equation in quantum mechanics which states that the energy E of a photon, known as photon energy, is proportional to its frequency ν: =.
Additionally, using equation f = c/λ, = where E is the photon's energy; λ is the photon's wavelength; c is the speed of light in vacuum; h is the Planck constant; The photon energy at 1 Hz is equal to 6.626 070 15 × 10 −34 J, which is equal to 4.135 667 697 × 10 −15 eV.
where v is the speed of the wave (c in a vacuum or less in other media), f is the frequency and λ is the wavelength. As waves cross boundaries between different media, their speeds change but their frequencies remain constant. Electromagnetic waves in free space must be solutions of Maxwell's electromagnetic wave equation. Two main classes of ...
Longer-wavelength radiation such as visible light is nonionizing; the photons do not have sufficient energy to ionize atoms. Throughout most of the electromagnetic spectrum, spectroscopy can be used to separate waves of different frequencies, so that the intensity of the radiation can be measured as a function of frequency or wavelength ...
is the speed of light (i.e. phase velocity) in a medium with permeability μ, and permittivity ε, and ∇ 2 is the Laplace operator. In a vacuum, v ph = c 0 = 299 792 458 m/s, a fundamental physical constant. [1] The electromagnetic wave equation derives from Maxwell's equations.
In a dispersive medium, the phase speed itself depends upon the frequency of the wave, making the relationship between wavelength and frequency nonlinear. In the case of electromagnetic radiation —such as light—in free space , the phase speed is the speed of light , about 3 × 10 8 m/s .
For example, for visible light, the refractive index of glass is typically around 1.5, meaning that light in glass travels at c / 1.5 ≈ 200 000 km/s (124 000 mi/s); the refractive index of air for visible light is about 1.0003, so the speed of light in air is about 90 km/s (56 mi/s) slower than c.
For example, a wavenumber in inverse centimeters can be converted to a frequency expressed in the unit gigahertz by multiplying by 29.979 2458 cm/ns (the speed of light, in centimeters per nanosecond); [5] conversely, an electromagnetic wave at 29.9792458 GHz has a wavelength of 1 cm in free space.