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Many laws take mathematical forms, and thus can be stated as an equation; for example, the law of conservation of energy can be written as =, where is the total amount of energy in the universe. Similarly, the first law of thermodynamics can be written as d U = δ Q − δ W {\displaystyle \mathrm {d} U=\delta Q-\delta W\,} , and Newton's ...
In chemistry, Le Chatelier's principle (pronounced UK: / l ə ʃ æ ˈ t ɛ l j eɪ / or US: / ˈ ʃ ɑː t əl j eɪ /) [1] is a principle used to predict the effect of a change in conditions on chemical equilibrium. [2] Other names include Chatelier's principle, Braun–Le Chatelier principle, Le Chatelier–Braun principle or the equilibrium ...
Lamm equation: Chemistry, Biophysics: Ole Lamm: Langmuir equation: Surface Chemistry: Irving Langmuir: Laplace transform Laplace's equation Laplace operator Laplace distribution Laplace invariant Laplace expansion Laplace principle Laplace limit See also: List of things named after Pierre-Simon Laplace: Mathematics Physics Probability Theory ...
The first established thermodynamic principle, which eventually became the second law of thermodynamics, was formulated by Sadi Carnot in 1824 in his book Reflections on the Motive Power of Fire. By 1860, as formalized in the works of scientists such as Rudolf Clausius and William Thomson , what are now known as the first and second laws were ...
The law of conservation of mass and the analogous law of conservation of energy were finally generalized and unified into the principle of mass–energy equivalence, described by Albert Einstein's equation =. Special relativity also redefines the concept of mass and energy, which can be used interchangeably and are defined relative to the frame ...
This is the most useful form of the second law of thermodynamics in chemistry, where free-energy changes can be calculated from tabulated enthalpies of formation and standard molar entropies of reactants and products. [19] [15] The chemical equilibrium condition at constant T and p without electrical work is dG = 0.
Ampère's circuital law; Bernoulli's equation; Bogoliubov–Born–Green–Kirkwood–Yvon hierarchy of equations; Bessel's differential equation; Boltzmann equation; Borda–Carnot equation; Burgers' equation; Darcy–Weisbach equation; Dirac equation. Dirac equation in the algebra of physical space; Dirac–Kähler equation; Doppler equations
Free-radical intermediate is stabilized by hyperconjugation; adjacent occupied sigma C–H orbitals donate into the electron-deficient radical orbital. A new method of anti-Markovnikov addition has been described by Hamilton and Nicewicz, who utilize aromatic molecules and light energy from a low-energy diode to turn the alkene into a cation ...