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A typical phase diagram for a single-component material, exhibiting solid, liquid and gaseous phases. The solid green line shows the usual shape of the liquid–solid phase line. The dotted green line shows the anomalous behavior of water when the pressure increases. The triple point and the critical point are shown as red dots.
In thermal equilibrium, each phase (i.e. liquid, solid etc.) of physical matter comes to an end at a transitional point, or spatial interface, called a phase boundary, due to the immiscibility of the matter with the matter on the other side of the boundary. This immiscibility is due to at least one difference between the two substances ...
Supercritical liquid–gas boundaries are lines in the pressure-temperature (pT) diagram that delimit more liquid-like and more gas-like states of a supercritical fluid. They comprise the Fisher–Widom line , the Widom line , and the Frenkel line .
The upper curve is the line of liquidus, and the lower curve is the line of solidus. In chemistry , materials science , and physics , the liquidus temperature specifies the temperature above which a material is completely liquid, [ 2 ] and the maximum temperature at which crystals can co-exist with the melt in thermodynamic equilibrium .
The construction of a liquid vapor phase diagram assumes an ideal liquid solution obeying Raoult's law and an ideal gas mixture obeying Dalton's law of partial pressure. A tie line from the liquid to the gas at constant pressure would indicate the two compositions of the liquid and gas respectively. [14]
When water vapor condenses (an equilibrium fractionation), the heavier water isotopes (18 O and 2 H) become enriched in the liquid phase while the lighter isotopes (16 O and 1 H) tend toward the vapor phase. [4] Phase transitions occur when the thermodynamic free energy of a system is non-analytic for some choice of thermodynamic variables (cf ...
At high liquid-gas ratios, liquid forms the continuous phase and at low values it forms the disperse phase. In plug and slug flow , gas flows faster than the liquid and the liquid forms a 'slug' which becomes detached and velocity decreases until the next liquid slug catches up.
The compressed fluid region is located to the left of the blue line (the liquid-vapor phase boundary). The international pictogram for compressed gases. A compressed fluid (also called a compressed or unsaturated liquid, [1] subcooled fluid or liquid) is a fluid under mechanical or thermodynamic conditions that force it to be a liquid. [2]