Search results
Results from the WOW.Com Content Network
Conversion and its related terms yield and selectivity are important terms in chemical reaction engineering.They are described as ratios of how much of a reactant has reacted (X — conversion, normally between zero and one), how much of a desired product was formed (Y — yield, normally also between zero and one) and how much desired product was formed in ratio to the undesired product(s) (S ...
In ETP, ethylene is dimerized to 1-butene, which is isomerized to 2-butenes. The 2-butenes are then subjected to metathesis with ethylene. Rhenium- and molybdenum-containing heterogeneous catalysis are used. Nowadays, only the "reverse" reaction is practiced, i.e., the conversion of ethylene and 2-butene to propylene: [2]
Structure of (acac)Rh(C 2 H 4)(C 2 F 4), distances (red) in picometers. [3]The bonding between alkenes and transition metals is described by the Dewar–Chatt–Duncanson model, which involves donation of electrons in the pi-orbital on the alkene to empty orbitals on the metal.
Representative processes include: [1] The Phillips Triolefin and the Olefin conversion technology. This process interconverts propylene with ethylene and 2-butenes. Rhenium and molybdenum catalysts are used. Nowadays, only the reverse reaction, i.e., the conversion of ethylene and 2-butene to propylene is industrially practiced, however. [6]
The simplest alkene, ethylene (C 2 H 4) (or "ethene" in the IUPAC nomenclature) is the organic compound produced on the largest scale industrially. [ 5 ] Aromatic compounds are often drawn as cyclic alkenes, however their structure and properties are sufficiently distinct that they are not classified as alkenes or olefins. [ 3 ]
In organic chemistry, ethenolysis is a chemical process in which internal olefins are degraded using ethylene (H 2 C=CH 2) as the reagent.The reaction is an example of cross metathesis.
A 3D model of ethyne (), the simplest alkyneIn organic chemistry, an alkyne is an unsaturated hydrocarbon containing at least one carbon—carbon triple bond. [1] The simplest acyclic alkynes with only one triple bond and no other functional groups form a homologous series with the general chemical formula C n H 2n−2.
The absence of LiCl induces an inner sphere reductive elimination to afford the trans-acetate stereochemistry to give the trans-1,4-adduct. The presence of LiCl displaces acetate with chloride due to its higher binding affinity, which forces an outer sphere acetate attack anti to the palladium, and affords the cis-acetate stereochemistry to ...