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Larger defects in an ordered structure are usually considered dislocation loops. For historical reasons, many point defects, especially in ionic crystals, are called centers: for example a vacancy in many ionic solids is called a luminescence center, a color center, or F-center. These dislocations permit ionic transport through crystals leading ...
F-center in an NaCl crystal. An F-center or color center or Farbe center (from the original German Farbzentrum, where Farbe means color and zentrum means center) is a type of crystallographic defect in which an anionic vacancy in a crystal lattice is occupied by one or more unpaired electrons.
Origin of title phenomenon in crystallographic defects. Shown is a two-dimensional slice through a primitive cubic crystal system showing the regular square array of atoms on one face (open circles, o), and with these, places where atoms are missing from a regular site to create vacancies, displaced to an adjacent acceptable space to create a Frenkel pair, or substituted by a smaller or larger ...
Crystals inherently possess imperfections, sometimes referred to as crystallographic defects. Vacancies occur naturally in all crystalline materials. At any given temperature, up to the melting point of the material, there is an equilibrium concentration (ratio of vacant lattice sites to those containing atoms). [ 2 ]
Comparison of fcc and hcp lattices, explaining the formation of stacking faults in close-packed crystals. In crystallography, a stacking fault is a planar defect that can occur in crystalline materials. [1] [2] Crystalline materials form repeating patterns of layers of atoms. Errors can occur in the sequence of these layers and are known as ...
A Schottky defect is an excitation of the site occupations in a crystal lattice leading to point defects named after Walter H. Schottky. In ionic crystals , this defect forms when oppositely charged ions leave their lattice sites and become incorporated for instance at the surface, creating oppositely charged vacancies .
The existence of a topological defect can be demonstrated whenever the boundary conditions entail the existence of homotopically distinct solutions. Typically, this occurs because the boundary on which the conditions are specified has a non-trivial homotopy group which is preserved in differential equations; the solutions to the differential equations are then topologically distinct, and are ...
Disclinations are topological defects because they cannot be created locally by an affine transformation without cutting the hexagonal array outwards to infinity (or the border of a finite crystal). The undisturbed hexagonal crystal has a 60° symmetry, but when a wedge is removed to create a 5-folded disclination, the crystal symmetry is ...