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For instance, to safely fill a new container or a pressure vessel with flammable gases, the atmosphere of normal air (containing 20.9 volume percent of oxygen) in the vessel would first be flushed (purged) with nitrogen or another non-flammable inert gas, thereby reducing the oxygen concentration inside the container. When the oxygen ...
In an oxygen system the presence of oxygen is implied, and in a sufficiently high partial pressure of oxygen, most materials can be considered fuel. Potential ignition sources are present in almost all oxygen systems, but fire hazards can be mitigated by controlling the risk factors associated with the oxygen, fuel, or heat, which can limit the ...
A 5% displayed LFL reading for methane, for example, would be equivalent to 5% multiplied by 4.4%, or approximately 0.22% methane by volume at 20 degrees C. Control of the explosion hazard is usually achieved by sufficient natural or mechanical ventilation, to limit the concentration of flammable gases or vapors to a maximum level of 25% of ...
The system can be flushed with an inert gas to reduce the concentration of oxygen so that when the flammable gas is admitted, an ignitable mixture cannot form. In NFPA 56, [1] this is known as purge-into-service. In combustion engineering terms, the admission of inert gas dilutes the oxygen below the limiting oxygen concentration.
Consider the first triangular diagram below, which shows all possible mixtures of methane, oxygen and nitrogen. Air is a mixture of about 21 volume percent oxygen, and 79 volume percent inerts (nitrogen). Any mixture of methane and air will therefore lie on the straight line between pure methane and pure air – this is shown as the blue air-line.
A non-flammable, nonpoisonous compressed gas (Division 2.2) means any material (or mixture) which: A non-flammable gas means any material that: Exerts in the packaging an absolute pressure of 280 kPa (40.6 psia) or greater at 20 °C (68 °F), and; Does not meet the definition of Division 2.1 or 2.3. The following applies to aerosols:
A pressure drop as small as 100 Torr (13 kPa), which produces no symptoms if it is gradual, may be fatal if it occurs suddenly. [77] One such incident occurred in 1983 in the North Sea , where violent explosive decompression from nine atmospheres to one caused four divers to die instantly from massive and lethal barotrauma . [ 79 ]
The original mass of flammable material and the mass of the oxygen consumed (typically from the surrounding air) equals the mass of the flame products (ash, water, carbon dioxide, and other gases). Lavoisier used the experimental fact that some metals gained mass when they burned to support his ideas (because those chemical reactions capture ...