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An example of this crystallization process is the production of Glauber's salt, a crystalline form of sodium sulfate. In the diagram, where equilibrium temperature is on the x-axis and equilibrium concentration (as mass percent of solute in saturated solution) in y-axis , it is clear that sulfate solubility quickly decreases below 32.5 °C.
In addition, physical properties are often controlled by crystalline defects. The understanding of crystal structures is an important prerequisite for understanding crystallographic defects. Most materials do not occur as a single crystal, but are poly-crystalline in nature (they exist as an aggregate of small crystals with different orientations).
Crystallization of polymers is a process associated with partial alignment of their molecular chains. These chains fold together and form ordered regions called lamellae , which compose larger spheroidal structures named spherulites .
A crystal's crystallographic forms are sets of possible faces of the crystal that are related by one of the symmetries of the crystal. For example, crystals of galena often take the shape of cubes, and the six faces of the cube belong to a crystallographic form that displays one of the symmetries of the isometric crystal system. Galena also ...
Example of the strongest (hydrogen bonds) and weakest (van der Waals) interactions in acetaminophen structure that influences the crystal structure. A supramolecular synthon is a pair of molecules that form relatively strong intermolecular interactions in the early phases of crystallization ; these molecule pairs are the basic structural motif ...
Fractional crystallization, or crystal fractionation, is one of the most important geochemical and physical processes operating within crust and mantle of a rocky planetary body, such as the Earth. It is important in the formation of igneous rocks because it is one of the main processes of magmatic differentiation . [ 1 ]
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Crystal growth is a major stage of a crystallization process, and consists of the addition of new atoms, ions, or polymer strings into the characteristic arrangement of the crystalline lattice. [ 1 ] [ 2 ] The growth typically follows an initial stage of either homogeneous or heterogeneous (surface catalyzed) nucleation , unless a "seed ...