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Pnictogen hydrides or hydrogen pnictides are binary compounds of hydrogen with pnictogen (/ ˈ p n ɪ k t ə dʒ ə n / or / ˈ n ɪ k t ə dʒ ə n /; from Ancient Greek: πνῑ́γω "to choke" and -gen, "generator") atoms (elements of group 15: nitrogen, phosphorus, arsenic, antimony, bismuth, and moscovium) covalently bonded to hydrogen.
Hydrazoic acid, also known as hydrogen azide, azic acid or azoimide, [2] is a compound with the chemical formula HN 3. [3] It is a colorless, volatile, and explosive liquid at room temperature and pressure. It is a compound of nitrogen and hydrogen, and is therefore a pnictogen hydride. It was first isolated in 1890 by Theodor Curtius. [4]
The salts produced by the action of ammonia on acids are known as the ammonium salts and all contain the ammonium ion ([NH 4] +). [38] Although ammonia is well known as a weak base, it can also act as an extremely weak acid. It is a protic substance and is capable of formation of amides (which contain the NH − 2 ion).
Ammonia solution, also known as ammonia water, ammonium hydroxide, ammoniacal liquor, ammonia liquor, aqua ammonia, aqueous ammonia, or (inaccurately) ammonia, is a solution of ammonia in water. It can be denoted by the symbols NH 3 (aq). Although the name ammonium hydroxide suggests a salt with the composition [NH + 4][OH −
Binary hydrogen compounds in group 1 are the ionic hydrides (also called saline hydrides) wherein hydrogen is bound electrostatically. Because hydrogen is located somewhat centrally in an electronegative sense, it is necessary for the counterion to be exceptionally electropositive for the hydride to possibly be accurately described as truly behaving ionic.
A Lewis base is also a Brønsted–Lowry base, but a Lewis acid does not need to be a Brønsted–Lowry acid. The classification into hard and soft acids and bases ( HSAB theory ) followed in 1963. The strength of Lewis acid-base interactions, as measured by the standard enthalpy of formation of an adduct can be predicted by the Drago–Wayland ...
Lithium tetramethylpiperidide (LiTMP or harpoon base) Other strong non-nucleophilic bases are sodium hydride and potassium hydride. These compounds are dense, salt-like materials that are insoluble and operate by surface reactions. Some reagents are of high basicity (pK a of
A metal hydride can be a thermodynamically a weak acid and a weak H − donor; it could also be strong in one category but not the other or strong in both. The H − strength of a hydride also known as its hydride donor ability or hydricity corresponds to the hydride's Lewis base strength. Not all hydrides are powerful Lewis bases.