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Acids and bases. A Lewis acid (named for the American physical chemist Gilbert N. Lewis) is a chemical species that contains an empty orbital which is capable of accepting an electron pair from a Lewis base to form a Lewis adduct. A Lewis base, then, is any species that has a filled orbital containing an electron pair which is not involved in ...
Lewis acid catalysis. In Lewis acid catalysis of organic reactions, a metal-based Lewis acid acts as an electron pair acceptor to increase the reactivity of a substrate. Common Lewis acid catalysts are based on main group metals such as aluminum, boron, silicon, and tin, as well as many early (titanium, zirconium) and late (iron, copper, zinc ...
Base (chemistry) Soaps are weak bases formed by the reaction of fatty acids with sodium hydroxide or potassium hydroxide. In chemistry, there are three definitions in common use of the word " base ": Arrhenius bases, Brønsted bases, and Lewis bases. All definitions agree that bases are substances that react with acids, as originally proposed ...
HSAB theory. HSAB is an acronym for "hard and soft (Lewis) acids and bases ". HSAB is widely used in chemistry for explaining the stability of compounds, reaction mechanisms and pathways. It assigns the terms 'hard' or 'soft', and 'acid' or 'base' to chemical species. 'Hard' applies to species which are small, have high charge states (the ...
Acid strength is the tendency of an acid, symbolised by the chemical formula , to dissociate into a proton, , and an anion, . The dissociation or ionization of a strong acid in solution is effectively complete, except in its most concentrated solutions. Examples of strong acids are hydrochloric acid , perchloric acid , nitric acid and sulfuric ...
Acids and bases. The Brønsted–Lowry theory (also called proton theory of acids and bases[1]) is an acid–base reaction theory which was first developed by Johannes Nicolaus Brønsted and Thomas Martin Lowry independently in 1923. [2][3] The basic concept of this theory is that when an acid and a base react with each other, the acid forms ...
Gilbert Newton Lewis ForMemRS [1] (October 23 [2][3][4] or October 25, 1875 – March 23, 1946) [1][5][6] was an American physical chemist and a dean of the college of chemistry at University of California, Berkeley. [3][7] Lewis was best known for his discovery of the covalent bond and his concept of electron pairs; his Lewis dot structures ...
In chemistry, an acid–base reaction is a chemical reaction that occurs between an acid and a base.It can be used to determine pH via titration.Several theoretical frameworks provide alternative conceptions of the reaction mechanisms and their application in solving related problems; these are called the acid–base theories, for example, Brønsted–Lowry acid–base theory.