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Carboxylic acids tend to have higher boiling points than water, because of their greater surface areas and their tendency to form stabilized dimers through hydrogen bonds. For boiling to occur, either the dimer bonds must be broken or the entire dimer arrangement must be vaporized, increasing the enthalpy of vaporization requirements significantly
In terms of chemical potential, at the boiling point, the liquid and gas phases have the same chemical potential. Adding a nonvolatile solute lowers the solvent’s chemical potential in the liquid phase, but the gas phase remains unaffected. This shifts the equilibrium between phases to a higher temperature, elevating the boiling point.
Boiling points of alkanes, alkenes, ethers, halogenoalkanes, aldehydes, ketones, alcohols and carboxylic acids as a function of molar mass. In general, compounds with ionic bonds have high normal boiling points, if they do not decompose before reaching such high temperatures. Many metals have high boiling points, but
The direct oxidation of primary alcohols to carboxylic acids normally proceeds via the corresponding aldehyde, which is transformed via an aldehyde hydrate (R−CH(OH) 2) by reaction with water before it can be further oxidized to the carboxylic acid. Mechanism of oxidation of primary alcohols to carboxylic acids via aldehydes and aldehyde hydrates
A cyclic ether and high-boiling solvent (b.p. 101.1 °C). Tetrahydrofuran (THF) A cyclic ether, one of the most polar simple ethers that is used as a solvent. Anisole (methoxybenzene) An aryl ether and a major constituent of the essential oil of anise seed. Crown ethers: Cyclic polyethers that are used as phase transfer catalysts.
Boiling point (°C) K b (°C⋅kg/mol) Freezing point (°C) K f (°C⋅kg/mol) Data source; Aniline: 184.3 3.69 –5.96 –5.87 K b & K f [1] Lauric acid: 298.9 44 –3.9 Acetic acid: 1.04 117.9 3.14 16.6 –3.90 K b [1] K f [2] Acetone: 0.78 56.2 1.67 –94.8 K b [3] Benzene: 0.87 80.1 2.65 5.5 –5.12 K b & K f [2] Bromobenzene: 1.49 156.0 6. ...
Some important classes of organic molecules are derivatives of alkanes, such as the primary alcohols, aldehydes, and (mono)carboxylic acids form analogous series to the alkanes. The corresponding homologous series of primary straight-chained alcohols comprises methanol (CH 4 O), ethanol (C 2 H 6 O), 1-propanol (C 3 H 8 O), 1-butanol , and so on.
This is a list of the various reported boiling points for the elements, with recommended values to be used elsewhere on Wikipedia. For broader coverage of this topic, see Boiling point . Boiling points, Master List format