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Dispersion is a process by which (in the case of solid dispersing in a liquid) agglomerated particles are separated from each other, and a new interface between the inner surface of the liquid dispersion medium and the surface of the dispersed particles is generated. This process is facilitated by molecular diffusion and convection. [4]
This model explains the origin of the electronic dispersion relation, but the explanation for band gaps is subtle in this model. [2]: 121 The second model starts from the opposite limit, in which the electrons are tightly bound to individual atoms. The electrons of a single, isolated atom occupy atomic orbitals with discrete energy levels.
b) A ball and stick diagram showing the asymmetric geometries about the Pb atoms c) A spacefill model showing how the proximity of bulky trimethylsilyl groups. Dispersion has been implicated in stabilizing a Ga-substituted doubly bonded dipnictenes of the form [L(X)Ga] 2 E 2 where E = As, Sb, Bi and L = C[C(Me)N(2,6-i Pr 2-C 6 H 3). [17]
Dispersion (chemistry), a system in which particles are dispersed in a continuous phase of a different composition; Dispersion (geology), a process whereby sodic soil disperses when exposed to water; Dispersion (materials science), the fraction of atoms of a material exposed to the surface; Dispersion polymerization, a polymerization process
In 1923, Peter Debye and Erich Hückel reported the first successful theory for the distribution of charges in ionic solutions. [7] The framework of linearized Debye–Hückel theory subsequently was applied to colloidal dispersions by S. Levine and G. P. Dube [8] [9] who found that charged colloidal particles should experience a strong medium-range repulsion and a weaker long-range attraction.
London dispersion forces (LDF, also known as dispersion forces, London forces, instantaneous dipole–induced dipole forces, fluctuating induced dipole bonds [1] or loosely as van der Waals forces) are a type of intermolecular force acting between atoms and molecules that are normally electrically symmetric; that is, the electrons are ...
Three dimensionality is best highlighted by the depictions of bonds, using wedges, bolding, and hashed formats. Some artists highlight three-dimensionality by varying fonts sizes, e.g. slightly larger fonts for the "front" atoms. In organic chemistry, double bonds and C-H bonds are shorter than most single bonds.
Hexane is a good example of a molecule with no polarity or highly electronegative atoms, yet is a liquid at room temperature due mainly to London dispersion forces. In this example, when one hexane molecule approaches another, a temporary, weak partially negative dipole on the incoming hexane can polarize the electron cloud of another, causing ...