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2-Bromoanisole is an organobromide with the formula BrC 6 H 4 OCH 3. A colorless liquid, it is one of three isomers of bromoanisole, the others being 3-bromoanisole and 4-bromoanisole . It is a standard coupling partner in metal catalyzed coupling reactions.
Available through Wiley Online Library [3] (John Wiley & Sons), SpecInfo on the Internet NMR is a collection of approximately 440,000 NMR spectra (organized as 13 C, 1 H, 19 F, 31 P, and 29 Si NMR databases). The data are accessed via the Internet using a Java interface and are stored in a server developed jointly with BASF. The software ...
A sample 19F NMR spectrum of a simple organic compound. Integrations are shown under each peak. 19F NMR spectrum of 1-bromo-3,4,5-trifluorobenzene. The expansion shows the spin–spin coupling pattern arising from the para-fluorine coupling to the 2 meta-fluorine and 2 ortho proton nuclei.
4-Bromoanisole is the organobromine compound with the formula CH 3 OC 6 H 4 Br. It is colorless liquid with a pleasant smell similar to that of anise seed. It is one of three isomers of bromoanisole, the others being 3-bromoanisole and 2-bromoanisole. It is the precursor to many 4-anisyl derivatives.
Methoxytoluenes (methylanisoles or cresyl methyl ethers) are a group of three isomeric organic compounds with the formula CH 3 OC 6 H 4 CH 3. They consist of a disubstituted benzene ring with methoxy group and one methyl group. All three are colorless flammable liquids which are soluble in organic solvents but poorly soluble in water.
tert-Butyl bromide (also referred to as 2-bromo-2-methylpropane) is an organic compound with the formula Me 3 CBr (Me = methyl). The molecule features a tert-butyl group attached to a bromide substituent. This organobromine compound is used as a standard reagent in synthetic organic chemistry. It is a colorless liquid.
CH 3 OC 6 H 5 + (CH 3 CO) 2 O → CH 3 OC 6 H 4 C(O)CH 3 + CH 3 CO 2 H. Unlike most acetophenones, but reflecting the influence of the methoxy group, methoxyacetophenone undergoes a second acetylation. Many related reactions have been demonstrated. For example, phosphorus pentasulfide (P 4 S 10) converts anisole to Lawesson's reagent, [(CH 3 OC ...
Bromoform was discovered in 1832 by Löwig who distilled a mixture of bromal and potassium hydroxide, as analogous to preparation of chloroform from chloral. [5]Bromoform can be prepared by the haloform reaction using acetone and sodium hypobromite, by the electrolysis of potassium bromide in ethanol, or by treating chloroform with aluminium bromide.